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・ Irene Amelia Morales Machado
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Ireland–Claisen rearrangement
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Ireland–Claisen rearrangement : ウィキペディア英語版
Ireland–Claisen rearrangement
The Ireland–Claisen rearrangement is a chemical reaction of an allylic ester with strong base to give an γ,δ-unsaturated carboxylic acid.
Several reviews have been published.
==Mechanism==
The Ireland–Claisen rearrangement is a type of Claisen rearrangement. The mechanism is therefore a concerted ()-sigmatropic rearrangement which according to the Woodward–Hoffmann rules show a concerted, suprafacial, pericyclic reaction pathway.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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